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Among the emerging materials, metal-organic framework (MOF)-based materials, including pristine MOFs, MOF composites, and MOF derivatives, have drawn tremendous attention due to their remarkable superiority over conventional materials for energy conversion and storage applications. 3
In conclusion, MOFs and MOF-derived nanomaterials show great potential in the field of energy storage and conversion due to their unique properties. Nonetheless, there are still issues and room for improvement in both the synthesis and pyrolysis processes of MOFs.
Recently, the applications of MOFs in energy fields such as fuel storage, photo-induced hydrogen evolution, fuel cells, batteries, and supercapacitors have experienced a new surge of interest in both the chemistry and materials science communities.
Other than metal oxides, diverse functional materials can be derived from MOFs by reacting MOFs with secondary reactants in the gas or liquid phase. This versatile strategy leads to easy synthesis of hydroxides (90, 91), sulfides (92 – 94), selenides (95), phosphides (96, 97), and phosphates (98) and their nanocomposites.
In addition to pristine MOFs, MOF derivatives such as porous carbons and nanostructured metal oxides can also exhibit promising performances in energy storage and conversion applications.
The search for novel materials in the storage and utilization of green energy to achieve low-carbon economy and sustainable development is a vital mission in materials science, and the emergence of MOFs can push this search to new levels.
ATES is a promising alternative to the traditional compression method of thermal storage such as sensible and latent heat storage. In ATES, the heat from a working fluid source such as water, methanol, ethanol and ammonia is absorbed by an adsorbent through an endothermic process and released through an exothermic process [3], [4], [5] general, latent …
This Forum Issue of ACS Applied Energy Materials focuses on the role that metal–organic frameworks (MOFs) play in energy storage, conversion, and utilization, spotlighting their …
Metal–organic frameworks (MOFs) have emerged as a versatile class of porous materials with tremendous potential for various applications, including energy storage devices. This review provides a comprehensive analysis of recent advancements and applications of MOFs in the field of energy storage including a brief overview of the fundamental aspects of …
In the present review, we precisely discuss the interesting properties of MOFs and the various methodologies for their synthesis, and also the future dependence on the …
Among these novel materials, metal–organic frameworks (MOFs), a class of porous materials, have gained increasing attention for utilization in energy storage and …
Metal–organic frameworks (MOFs), a novel type of porous crystalline materials, have attracted increasing attention in clean energy applications due to their high surface area, …
Metal ions or clusters that have been bonded with organic linkers to create one- or more-dimensional structures are referred to as metal–organic frameworks (MOFs). Reticular synthesis also forms MOFs with properly designated components that can result in crystals with high porosities and great chemical and thermal stability. Due to the wider surface area, huge …
Despite previous unsuccessful attempts to commercialize metal-organic frameworks (MOFs), these materials are now finding opportunities as energy-efficient alternatives for a range of critical technologies that demand high-energy inputs. These include carbon capture, water harvesting for potable water production and HVAC systems, and various chemical separations and …
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The first-generation plants will use commercially available sorbents, but the development of metal-organic frameworks (MOFs) — a class of porous materials with tunable …
Other than metal oxides, diverse functional materials can be derived from MOFs by reacting MOFs with secondary reactants in the gas or liquid phase. This …
Coordination polymers are compounds formed by the assembly of metal ions or metal clusters with organic ligands through coordination bonds. 5,6 The more prominent of these are porous coordination polymers with pore structures. Porous coordination polymers formed from ligands with metal ions/metal clusters are commonly referred to as metal–organic frameworks. 7 Since …
MOFs contain strong coordination of metals with ligands, whose open frameworks are characterized by high permanent porosity, high crystallinity, and long-range …
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In an illustrative example, Garcia, Smit and colleagues ranked over 1,200 materials based on 6 reference key performance indicators (KPIs): Henry selectivity (that is, the ratio of CO 2 and N 2 ...
In summary, MOFs are promising precursors or sacrificial templates for preparing various advanced functional materials with desired compositions, morphologies, …
Methane fugitive emissions from coal mining constitute a significant contribution to greenhouse gases, even after exploitation closure (Pavloudakis et al., 2020; Gao et al., 2020).Typically, methane is emitted discontinuously through mining ventilation air in concentrations between 0.1 and 1% (Su et al., 2005).The flow rates of ventilation air methane …
Given the accelerated world energy demand for economic and civilization improvement, huge reliance on fossil fuels has raised critical environmental problems as huge (CO 2) emissions in the atmosphere, close to 410 ppm in 2019, is the main reason to be the cause for world climate change.Some reason for this kind of situation is development & …
MOFs are attractive supporting materials for the encapsulation of PCMs due to their unique merits (ultrahigh active surface area, ultrahigh porosity, tunable pore size, and …
Abstract Metal–organic frameworks (MOFs) and covalent organic frameworks (COFs) as two burgeoning families of crystalline porous materials (CPMs) have been extensively investigated and applied in various fields on account of their enticing features as large surface area, controllable crystalline structure and highly ordered pores/channels. However, the greatest …
